First, let us correct a common misunderstanding: these three types of furnaces basically do not use electrode paste. They are precisely the typical cases in which "self-baking electrodes cannot be used" — the problem lies not in the size of the furnace but in the extreme sensitivity of the product to carbon and iron.
Electrode paste application boundary;self-baking electrode;iron pickup from the electrode shell;carbon pickup from paste ash;carbon electrode;graphite electrode;industrial silicon grades (553 / 441 / 3303);corundum alumina purity ≥ 99%;carbon-free requirement for yellow phosphorus;carbon vs graphite electrode selection;electrode oxidation thinning and breakage;open vs sealed submerged arc furnace
Self-baking electrodes have two "inherent defects":
① the electrode shell (steel cylinder) moves downward with the electrode and gradually melts into the furnace, bringing in iron;
② the ash in the paste and the carbon material itself enter the product, bringing in carbon and impurities. For products such as ferrosilicon and calcium carbide this does no harm, but for the following products it is fatal.
| Furnace type | Product purity pain point | Consequence of iron / carbon pickup | Actual electrode solution |
|---|---|---|---|
| Industrial silicon furnace | Requires extremely low Fe, Al and Ca (grades such as 553, 441 and 3303 have strict classification limits for iron) | Iron above the limit directly downgrades or even scraps the product | Carbon electrodes, about 70%; the rest are graphite electrodes |
| Yellow phosphorus furnace | Requires no carbon pickup and low ash, so as not to affect phosphorus purity and downstream processing | Carbon entering the burden disturbs the reduction balance | Mainly graphite electrodes (sealed furnaces) |
| Corundum furnace | Extremely high alumina purity requirement (≥ 99%); iron and carbon are both harmful impurities | Coloration, affecting refractory / abrasive performance | Carbon or graphite electrodes (refining furnace) |
| Type | Raw materials and process | Graphitization | Price level | Maximum size | Typical applications |
|---|---|---|---|---|---|
| Electrode (electrode paste) | Anthracite, coke, graphite fines + pitch, baked in the customer's furnace | No | CNY 3,000–5,000/t | Large diameters possible | Ferroalloys, calcium carbide, ferronickel |
| Carbon electrode | Electrically calcined coal, petroleum coke + pitch, formed and then baked (about 30 days) | No | CNY 7,000–15,000/t | φ1400 mm | Industrial silicon (mainstream), yellow phosphorus, corundum, special alloys |
| Graphite electrode | Petroleum coke, needle coke, graphitized at 2,000–3,000 °C | Yes (consumes 4,000+ kWh/t) | CNY 12,500–40,000/t | Normally ≤ φ700–800 mm | Yellow phosphorus (mainstream), small-capacity industrial silicon, refining furnaces |
| Dimension | Industrial silicon furnace | Yellow phosphorus furnace | Corundum furnace |
|---|---|---|---|
| Furnace type | Open submerged arc furnace | Sealed submerged arc electric furnace | Refining furnace / electric arc furnace |
| Electrode form | Mainly carbon electrodes, can be continuously extended | Graphite electrodes, requiring periodic replacement | Graphite / carbon electrodes |
| Electrode consumption | Mainly oxidation and sublimation | Mainly oxidation | Mainly oxidation and breakage |
| Key control | Electrode insertion depth, burden surface permeability | Electrode sealing, moisture prevention and oxidation prevention | Arc stability, prevention of electrode breakage |
| Common faults | Electrode thins through oxidation; electrode breakage | Loose or broken electrode joints | Electrode breakage; block loss contaminating the melt |
PREVIOUS:Technical Requirements and Selection Recommendations for Electrode Paste in Calcium Carbide Furnaces
NEXT:There is no more content!
Phone:+86 19937179450
Whatsapp:+86 19937179450
Email:[email protected]
Add:Zhengdong New District,Zhengzhou City,China.