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How Does Electrode Paste Differ for Yellow Phosphorus Furnaces, Corundum Furnaces and Industrial Sil

Time:2026-11-04   Traffic:1019
Abstract

First, let us correct a common misunderstanding: these three types of furnaces basically do not use electrode paste. They are precisely the typical cases in which "self-baking electrodes cannot be used" — the problem lies not in the size of the furnace but in the extreme sensitivity of the product to carbon and iron.

Keywords

Electrode paste application boundary;self-baking electrode;iron pickup from the electrode shell;carbon pickup from paste ash;carbon electrode;graphite electrode;industrial silicon grades (553 / 441 / 3303);corundum alumina purity ≥ 99%;carbon-free requirement for yellow phosphorus;carbon vs graphite electrode selection;electrode oxidation thinning and breakage;open vs sealed submerged arc furnace

Last updated: 2026-11-04 Owner: Rongxing Group Technical Team

1. Why self-baking electrodes cannot be used

Self-baking electrodes have two "inherent defects":

① the electrode shell (steel cylinder) moves downward with the electrode and gradually melts into the furnace, bringing in iron;

② the ash in the paste and the carbon material itself enter the product, bringing in carbon and impurities. For products such as ferrosilicon and calcium carbide this does no harm, but for the following products it is fatal.

Furnace typeProduct purity pain pointConsequence of iron / carbon pickupActual electrode solution
Industrial silicon furnaceRequires extremely low Fe, Al and Ca (grades such as 553, 441 and 3303 have strict classification limits for iron)Iron above the limit directly downgrades or even scraps the productCarbon electrodes, about 70%; the rest are graphite electrodes
Yellow phosphorus furnaceRequires no carbon pickup and low ash, so as not to affect phosphorus purity and downstream processingCarbon entering the burden disturbs the reduction balanceMainly graphite electrodes (sealed furnaces)
Corundum furnaceExtremely high alumina purity requirement (≥ 99%); iron and carbon are both harmful impuritiesColoration, affecting refractory / abrasive performanceCarbon or graphite electrodes (refining furnace)

2. The essential differences among the three types of electrodes

TypeRaw materials and processGraphitizationPrice levelMaximum sizeTypical applications
Electrode (electrode paste)Anthracite, coke, graphite fines + pitch, baked in the customer's furnaceNoCNY 3,000–5,000/tLarge diameters possibleFerroalloys, calcium carbide, ferronickel
Carbon electrodeElectrically calcined coal, petroleum coke + pitch, formed and then baked (about 30 days)NoCNY 7,000–15,000/tφ1400 mmIndustrial silicon (mainstream), yellow phosphorus, corundum, special alloys
Graphite electrodePetroleum coke, needle coke, graphitized at 2,000–3,000 °CYes (consumes 4,000+ kWh/t)CNY 12,500–40,000/tNormally ≤ φ700–800 mmYellow phosphorus (mainstream), small-capacity industrial silicon, refining furnaces

3. Operating differences among the three furnace types

DimensionIndustrial silicon furnaceYellow phosphorus furnaceCorundum furnace
Furnace typeOpen submerged arc furnaceSealed submerged arc electric furnaceRefining furnace / electric arc furnace
Electrode formMainly carbon electrodes, can be continuously extendedGraphite electrodes, requiring periodic replacementGraphite / carbon electrodes
Electrode consumptionMainly oxidation and sublimationMainly oxidationMainly oxidation and breakage
Key controlElectrode insertion depth, burden surface permeabilityElectrode sealing, moisture prevention and oxidation preventionArc stability, prevention of electrode breakage
Common faultsElectrode thins through oxidation; electrode breakageLoose or broken electrode jointsElectrode breakage; block loss contaminating the melt

PREVIOUS:Technical Requirements and Selection Recommendations for Electrode Paste in Calcium Carbide Furnaces

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